diff --git a/.chloggen/configgrpc-remove-deprecated.yaml b/.chloggen/configgrpc-remove-deprecated.yaml
new file mode 100644
index 00000000000..ccdd3ca63b7
--- /dev/null
+++ b/.chloggen/configgrpc-remove-deprecated.yaml
@@ -0,0 +1,25 @@
+# Use this changelog template to create an entry for release notes.
+
+# One of 'breaking', 'deprecation', 'new_component', 'enhancement', 'bug_fix'
+change_type: breaking
+
+# The name of the component, or a single word describing the area of concern, (e.g. otlpreceiver)
+component: configgrpc
+
+# A brief description of the change.  Surround your text with quotes ("") if it needs to start with a backtick (`).
+note: Removed deprecated `ClientConfig.ToClientConnWithOptions`/`ServerConfig.ToServerWithOptions`.
+
+# One or more tracking issues or pull requests related to the change
+issues: [11359, 9480]
+
+# (Optional) One or more lines of additional information to render under the primary note.
+# These lines will be padded with 2 spaces and then inserted directly into the document.
+# Use pipe (|) for multiline entries.
+subtext: "These methods were renamed to `ClientConfig.ToClientConn`/`ServerConfig.ToServer` in v0.111.0."
+
+# Optional: The change log or logs in which this entry should be included.
+# e.g. '[user]' or '[user, api]'
+# Include 'user' if the change is relevant to end users.
+# Include 'api' if there is a change to a library API.
+# Default: '[user]'
+change_logs: [api]
diff --git a/config/configgrpc/configgrpc.go b/config/configgrpc/configgrpc.go
index 53bfbf79e69..831573115d2 100644
--- a/config/configgrpc/configgrpc.go
+++ b/config/configgrpc/configgrpc.go
@@ -264,18 +264,6 @@ func (gcs *ClientConfig) ToClientConn(
 	return grpc.NewClient(gcs.sanitizedEndpoint(), grpcOpts...)
 }
 
-// ToClientConnWithOptions is the same as [ClientConfig.ToClientConn].
-//
-// Deprecated: [v0.111.0] Use [ClientConfig.ToClientConn] instead.
-func (gcs *ClientConfig) ToClientConnWithOptions(
-	ctx context.Context,
-	host component.Host,
-	settings component.TelemetrySettings,
-	extraOpts ...ToClientConnOption,
-) (*grpc.ClientConn, error) {
-	return gcs.ToClientConn(ctx, host, settings, extraOpts...)
-}
-
 func (gcs *ClientConfig) getGrpcDialOptions(
 	ctx context.Context,
 	host component.Host,
@@ -408,18 +396,6 @@ func (gss *ServerConfig) ToServer(
 	return grpc.NewServer(grpcOpts...), nil
 }
 
-// ToServerWithOptions is the same as [ServerConfig.ToServer].
-//
-// Deprecated: [v0.111.0] Use [ServerConfig.ToServer] instead.
-func (gss *ServerConfig) ToServerWithOptions(
-	ctx context.Context,
-	host component.Host,
-	settings component.TelemetrySettings,
-	extraOpts ...ToServerOption,
-) (*grpc.Server, error) {
-	return gss.ToServer(ctx, host, settings, extraOpts...)
-}
-
 func (gss *ServerConfig) getGrpcServerOptions(
 	host component.Host,
 	settings component.TelemetrySettings,